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BCR改进法分析某铜矿生态修复示范地土壤基质中重金属形态

  • 作者:
  • 钟萍丽

  • 作者单位:
  • 低品位难处理黄金资源综合利用国家重点实验室& 厦门紫金矿冶技术有限公司
  • 详细信息:

  • 作者简介:
  • 钟萍丽(1991—),女,工程师,硕士,研究方向为矿山生态修复和废水处理;E‑mail:965966068@qq. com
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Analysis of heavy metal speciation in soil matrices of an ecological restoration demonstration site of a copper mine using the improved BCR method

  • English Author:
  • Zhong Pingli¹,²

  • Unit:
  • (1. State Key Laboratory of Comprehensive Utilization of Low‑grade Refractory Gold Resources; 2. Xiamen Zijin Mining and Metallurgy Technology Co., Ltd.)
  • 摘要
  • 在线预览
  • 参考文献

摘要:

重金属的赋存形态对其生物有效性、环境危害性等具有重要影响。采用 BCR改进法对某铜矿生态修复示范地土壤基质中和渣和黄土中重金属元素的赋存形态进行分析。结果表明:该铜矿生态修复示范地土壤基质中和渣和黄土样品中的Cu、Zn、As、Pb、Cr、Ni、Cd等重金属总量均符合 GB 36600—2018《土壤环境质量 建设用地土壤污染风险管控标准(试行)》第二类用地管制值;中和渣和黄土中重金属元素的赋存形态以残渣态为主,稳定性强,迁移活性弱,对环境潜在危害性小。中和渣中重金属元素的稳定性表明其作为土壤基质具有较可靠的环境安全性,利用中和渣复配自然土壤进行生态修复和植物复垦是可行的。  

关键词:

BCR改进法;生态修复;重金属形态;中和渣;黄土

Abstract:

The speciation of heavy metals is crucial for their bioavailability, environmental toxicity, and other aspects. The improved BCR method was used to study the speciation of heavy metals in the neutralized slag and loess in the soil matrix in an ecological restoration demonstration site of a copper mine. The results show that the total contents of heavy metals, such as Cu, Zn, As, Pb, Cr, Ni, and Cd, in the neutralized slag and loess in the soil matrix in the ecological restoration demonstration site of the copper mine all meet the second-class land control values specified in GB 36600-2018 Soil Environmental Quality Risk Control Standard for Soil Contamination of Development Land (Trial). The speciation of heavy metals in the neutralized slag and loess is predominantly in the residual fraction, which is highly stable, weakly mobile, and poses minimal potential environmental hazards. The stability of the heavy metals in the neutralized slag indicates its reliable environmental safety as a soil matrix. Using neutralized slag blended with natural soil for ecological restoration and phytoremediation is feasible.

Keywords:

improved BCR method; ecological restoration; heavy metal speciation; neutralized slag; loess