铜熔炼渣是火法造锍捕金过程中产生的冶炼废渣，建立渣中铅、锌、镍等杂质元素的测定方法对底吹炉熔炼工艺控制极为重要。实验采用硝酸、盐酸、氢氟酸、高氯酸溶解样品，采用电感耦合等离子体原子发射光谱法测定铅、锌、镍、锑、铋、砷，选择Pb 220.353 nm、Zn 213.856 nm、Ni 231.604 nm、Sb 206.833 nm、Bi 190.241 nm、As 193.75 nm作为分析谱线。实验结果表明：当校准曲线的线性范围为0～100 mg/L时，线性相关系数均大于0.999；铅、锌、镍、锑、铋、砷方法检出限分别为0.002 7 mg/L、0.000 6 mg/L、0.000 9 mg/L、0.008 4 mg/L、0.006 3 mg/L、0.014 4 mg/L；测定结果的相对标准偏差为0.15 %～4.45 %，加标回收率为98.48 %～104.44 %。该方法准确度和精密度良好，满足实际生产需求。

Copper smelting slag is the smelting residual from pyrogenic process of matte production and gold collection.It is very important to establish the determination method for impurities such as Pb,Zn and Ni for the control of bottom blowing furnace smelting process.The experiment uses nitric acid,hydrochloric acid,hydrofluoric acid,perchloric acid to dissolve samples,inductive coupled plasma-atomic emission spectrometry to determine Pb,Zn,Ni,Sb,Bi and As,and chooses Pb 220.353 nm,Zn 213.856 nm,Ni 231.604 nm,Sb 206.833 nm,Bi 190.241 nm and As 193.75 nm as the analysis spectrum line.The results show that when the linearity range of calibration curve is 0-100 mg/L,the related linear coefficients all exceeds 0.999;the detection limits of Pb,Zn,Ni,Sb,Bi and As are 0.002 7 mg/L,0.000 6 mg/L,0.000 9 mg/L,0.008 4 mg/L,0.006 3 mg/L and 0.014 4 mg/L;the RSD of determination results is 0.15 %-4.45 %,the recovery rate of reference materials is 98.48 %-104.44 %.The method is accurate and precise and can meet the requirement of actual production.