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锌冶炼渣资源化利用试验研究

  • 作者:
  • 毕廷涛|杨子轩|吴咪娜|王舒婷|孙晶
  • 作者单位:
  • 云南省生态环境科学研究院|云南省生态环境科学研究院|云南省生态环境科学研究院|云南省生态环境科学研究院|云南省生态环境科学研究院
  • 基金项目:

  • 国家自然科学基金项目(51764024)
  • 详细信息:

  • 作者简介:
  • 毕廷涛(1988—),男,云南楚雄人,高级工程师,从事环境工程研究工作;昆明市气象路王家坝23号,云南省生态环境科学研究院,650093;E-mail:btt317@qq.com
  • 通讯作者:
  • isnull
  • PDF下载

Experimental research on utilization of zinc smelting slag as resources

  • English Author:
  • Yunnan Research Academy of Eco-environmental Sciences|Yunnan Research Academy of Eco-environmental Sciences|Yunnan Research Academy of Eco-environmental Sciences|Yunnan Research Academy of Eco-environmental Sciences|Yunnan Research Academy of Eco-environmental Sciences
  • Unit:
  • 摘要
  • 在线预览
  • 参考文献

摘要:

锌冶炼渣作为重要的二次资源,含有大量有价金属,具有资源化利用价值。某锌冶炼企业产生的锌冶炼渣中银品位418 g/t,铅品位8.98 %,采用氯盐法浸出回收铅和银。试验分别考察了氯化钠、氯酸钠、盐酸用量,浸出温度、时间和液固比等对铅和银浸出率的影响。结果表明:在氯化钠用量410 g/L,盐酸用量10 mL,液固比9∶1,浸出温度90 ℃的条件下充分浸出2.5 h,铅和银的浸出率分别为95.4 %和90.5 %。

关键词:

锌冶炼渣;资源化;氯盐法;铅;银

Abstract:

As important secondary resource,zinc smelting slag contains a large amount of valuable metals,making it worth utilizing as resources.For the waste slag produced by a domestic zinc smelting enterprise,the silver grade is 418 g/t and the lead grade is 8.98 %.The lead and silver are leached and recovered by the chloride salt method.The effects of the amount of sodium chloride,sodium chlorate and hydrochloric acid,leaching temperature,leaching time and liquid-solid ratio on the leaching rate of lead and silver were investigated respectively.The best process conditions are as follows:sodium chloride dosage is 410 g/L,hydrochloric acid dosage is 10 mL,liquid-solid ratio is 91,and leaching temperature is 90 for full leaching for 2.5 h.Under the best conditions,the leaching rates of lead and silver are 95.4 % and 90.5 %,respectively.

Keywords:

zinc smelting slag;utilization as resources;chloride salt method;lead;silver