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首页 > 选矿与冶炼

湿法提金技术发展历程及应用现状

何志强|李栋|田庆华|郭学益|张磊
作者单位：
中南大学冶金与环境学院|中南大学冶金与环境学院|中南大学冶金与环境学院|中南大学冶金与环境学院|中南大学冶金与环境学院
基金项目：
国家重点研发计划“固废资源化”重点专项项目（2018YFC1902501）；湖南省环保厅环境保护科研课题
详细信息：
作者简介：
何志强（1997—），男，湖南桂阳人，硕士研究生，研究方向为非氰提金及含贵金属固废资源化处理；长沙市岳麓区麓山南路932号，中南大学冶金与环境学院，410083；E-mail:he15243550332@csu.edu.cn
通讯作者：
E-mail:qinghua@csu.edu.cn,0731-88877863
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Development history and current application status of wet gold extraction technology

English Author：
School of Metallurgy and Environment,Central South University|School of Metallurgy and Environment,Central South University|School of Metallurgy and Environment,Central South University|School of Metallurgy and Environment,Central South University|School of Metallurgy and Environment,Central South University
Unit：

摘要
在线预览
参考文献

摘要:

湿法提金技术由于具有工艺成熟、适应性强、相对于火法能耗低等优点，被广泛应用于黄金生产中。介绍了氰化法、硫脲法、氯化法、硫代硫酸盐法、多硫化物法及石硫合剂法等湿法提金技术的原理，分析了其优缺点，总结了湿法提金技术的发展历程及应用现状，展望了湿法提金技术的发展前景。

关键词:

湿法提金；氰化法；硫脲法；氯化法；硫代硫酸盐法；多硫化物法；石硫合剂法

Abstract:

Wet gold extraction technology is widely used in gold production because of its advantages such as mature technology,high adaptability and low energy consumption compared with fire extraction.In this paper,the mechanism of gold extraction technology such as cyanidation method,thiourea method,chlorination method,thiosulfate method,polysulfide method and lime sulfur method is introduced,their advantages and disadvantages are analyzed,the development history and current application status of wet gold extraction technology are summarized,and the development of wet gold extraction technology is prospected.

Keywords:

wet gold extraction;cyanidation method;thiourea method;chlorination method;thiosulfate method;polysulfide method;lime sulfur method

[1]胡春融,杨凤,杨廻春.黄金选冶技术现状及发展趋势[J].黄金,2006,27(7):29-36.
[2]殷璐,金哲男,杨洪英，等.我国黄金资源综合利用现状与展望[J].黄金科学技术,2018,26(1):17-24.
[3]许勇.黄金工业应用正推进产业高端化转型[N].中国黄金报,2021-01-08(002).
[4]石同吉.氰化提金技术发展现状评述[J].黄金科学技术,2001,9(6):22-29.
[5]李健,王鹏,赵国惠,等.某含金原生矿石沸腾焙烧—氰化提金工艺试验研究[J].黄金,2021,42(8):71-75.
[6]张力先.氰化提金工艺的最新进展[J].黄金学报,2001(2):124-130.
[7]肖力,王永良,钱鹏,等.非氰提金技术研究进展[J].黄金科学技术,2019,27(2):292-301.
[8]李骞，沈煌，张雁，等.硫脲浸金研究进展[J].黄金，2018，39（1）：66-69.
[9]胡杨甲,贺政,赵志强,等.非氰浸金技术发展现状及应用前景[J].黄金,2018,39(4):53-58.
[10]钟晋,胡显智,字富庭,等.硫代硫酸盐浸金现状与发展[J].矿冶,2014,23(2):65-69.
[11]曹昌琳,胡洁雪,龚乾.低浓度硫代硫酸盐浸金[J].中国有色金属学报,1992,2(4):33-36.
[12]石嵩高,李世祯.ZLT氯化法浸出金、银新工艺[J].黄金,2010,31(2):37-40.
[13]李桂春,卢寿慈.非氰化提金技术的发展[J].中国矿业,2003,12(3):1-5.
[14]张箭,兰新哲,丁峰,等.一种新的非氰提金方法[J].黄金,1993,14(10):40-43.
[15]郁能文,张箭.石硫合剂(LSSS)法浸金的电化学研究[J].黄金,1998,19(2):3-5.
[16]周文波,刘涛,吴卫国,等.金的提取技术[J].矿业快报,2006(2):14-17.
[17]玉涵,胡显智.氰化及非氰化提金方法综述[J].云南冶金,2010,39(3):9-12.
[18]简椿林.黄金冶炼技术综述[J].湿法冶金,2008,27(1):1-6.
[19]闫晓慧,李桂春,孟齐.金矿中提金技术的研究进展[J].应用化工,2019,48(11):2719-2723.
[20]苏玉花.姚安金矿全泥氰化—炭浆法提金实验研究[J].甘肃科技,2018,34(12):31-32.
[21]张彩轩.全泥氰化炭浆提金工艺在我国的应用[J].有色矿山,1988(12):32-36.
[22]邝金才,姚香.国内金精矿氰化提金技术现状[J].有色矿冶,2003(2):16-21.
[23]王笃军.氰化法在堆浸提金工艺的应用和研究[J].科技创新导报,2017,14(35):66-67.
[24]彭剑秋.国内外难选冶金矿三项提金新工艺新技术与标准规范应用手册[M].北京:冶金工业出版社,2006．
[25]张明洋.堆浸工艺在低品位黄金矿山中的应用[J].现代矿业,2017,33(8):302-304.
[26]邱显扬,杨永斌,戴子林.氰化提金工艺的新进展[J].矿冶工程,1999，19(3):7-9,21.
[27]刘洋,胡显智,魏志聪.助浸剂在氰化提金中的研究进展[J].矿冶,2011,20(2):57-62.
[28]蔡世军,王玲玲.氨氰浸金技术在老柞山金矿的应用[J].黄金,2001,22(1):45-47.
[29]刘玉雷,张清波,文扬思,等.广西龙头山金矿石富氧浸出工业试验研究[J].黄金,1998,19(10):3-5.
[30]王周谭.无氰浸金技术在我国的研究应用现状[J].黄金科学技术,1995,3(6):9-14.
[31]代淑娟,韩跃新,尹文新,等.某难浸浮选金精矿碱式预处理-氰化提金工艺[J].有色金属,2006(4):44-47.
[32]许晓阳,蔡创开,丁文涛.某难处理金矿热压预氧化—氰化工艺研究[J].黄金科学技术,2014,22(4):135-138.
[33]WANGJ,WANGW,DONGKW,etal.Researchonleachingofcarbonaceousgoldorewithcopper-ammonia-thiosulfatesolutions[J].MineralsEngineering,2019,137:232-240.
[34]FUPF,LIZY,FENGJ,etal.Recoveryofgoldandironfromcyanidetailingswithacombineddirectreductionroastingandleachingprocess[J].Metals,2018,8(7):561-574.
[35]CAOP,ZHANGSH,ZHENGYJ,etal.Differencesofcyanideleach-ingbetweencalcineanddustfromrefractorygoldconcentrates[J].TransactionsofNonferrousMetalsSocietyofChina,2020,30(7):1964-1979.
[36]杨洪英,范金,崔日成,等.难处理高砷金矿的细菌氧化-提金研究[J].贵金属,2009,30(3):1-3,20.
[37]LUOWJ,YANGHY,JINZN.Studyonthegoldrecoveryofdoublerefractorygoldoreconcentratebybiologicaloxidationpretreatment[J].AdvancedMaterialsResearch,2015,1130:379-382.
[38]孔德晶,孟春瑜,张启梁,等.难处理金银精矿生物氧化—氰化浸金试验研究[J].黄金,2016,37(5):59-62.
[39]RICHMONDKA,WILLIAMS,JONASAM.Alkalinecyanideleachingofrefractorygoldflotationconcentratesandbio-oxidisedproducts:Theeffectofprocessvariables[J].Hydrometallurgy,2018,179:79-93.
[40]汪勇,高起方,姜亚雄,等.云南某金铜混合矿选矿试验研究[J].矿冶,2017,26(4):23-26.
[41]苏保全.内蒙石英脉型金矿石氰化炭浆法提金工艺优化研究[D].包头:内蒙古科技大学,2019.
[42]JEFFREYMI，RITCHIEIM.TheleachingofgoldincyanidesolutionsinthepresenceofimpuritiesI.Theeffectoflead[J].JournalofTheElectrochemicalSociety,2019,147(9):3257-3262.
[43]YANGYB,LAIMX,ZHONGQ,etal.Studyonintensificationbehaviorofbismuthionsongoldcyanideleaching[J].Metals,2019,9(3):362-375.
[44]HANJH,LIXA,DAISJ.Electrochemicalinfluenceofquartzoncyanideleachingofgold[J].ChemicalPhysicsLetters,2020,739:136997.
[45]许晓阳.难处理金矿石加压氧化—氰化提金技术研究[J].黄金,2020,41(4):50-53.
[46]YUSM,YUTT,SONGWP,etal.Ultrasound-assistedcyanideextractionofgoldfromgoldconcentrateatlowtemperature[J].UltrasonicsSonochemistry,2020,64:105039.
[47]李骞，董斯宇，许瑞，等.金矿提金技术及其研究进展[J].黄金,2020,41(9):86-101.
[48]KIANINIAY,KHALESIMR,ABDOLLAHYM,etal.Predictingcyanideconsumptioningoldleaching:Akineticandthermodynamicmodelingapproach[J].Minerals,2018,8(3):110-123.
[49]BETANCOURTBUITRAGOLA,HERNANDEZRAMIREZA,COLINAMARQUEZJA,etal.Recentdevelopmentsinthephotocatalytictreatmentofcyanidewastewater:Anapproachtoremediationandrecoveryofmetals[J].Processes,2019,7(4):225-248.
[50]HOUDZ,LIUL,YANGQX,etal.Decompositionofcyanidefromgoldleachingtailingsbyusingsodiummetabisulphiteandhydrogenperoxide[J].AdvancesinMaterialsScienceandEngineering,2020(3):1-7.
[51]王中海.碱性硫脲提金体系稳定性的试验研究[D].赣州:江西理工大学,2008.
[52]唐林生,傅丽荣.非氰浸金剂研究进展（上）[J].中国化工,1995(5):31-32.
[53]张兴仁.提金工艺的新进展[J].矿产综合利用,1991(4):20-28.
[54]孟齐.非氰浸金技术现状及应用前景[J].云南化工,2018,45(6):19-20.
[55]萨本嘉,张方宇,程华.碱性硫脲溶金的研究[J].黄金,1984，5(3):45-47.
[56]CHAILY,OKIDOM,WEIWZ.EffectofNa2SO3onelectrochemi-calaspectsofgolddissolutioninalkalinethioureasolution[J].Hydrometallurgy,1999,53(3):255-266.
[57]郑粟,王云燕,柴立元.基于配位理论的碱性硫脲选择性溶金机理[J].中国有色金属学报,2005，15(10):153-159.
[58]白安平,宋永胜,李文娟,等.增氧条件下的碱性硫脲浸金实验[J].中国有色金属学报,2017,27(11):2363-2369.
[59]郭观发,胡岳华,邱冠周.硫脲提金理论研究——金溶解动力学[J].黄金,1994,15(9):30-33.
[60]胡岳华,郭观发,邱冠周,等.硫脲浸金机理的电化学研究[J].黄金科学技术,1995,3(2):43-48.
[61]DENGTL,LIAOMX,WANGMH,etal.Enhancementofgoldextractionfrombiooxidationresiduesusinganacidicsodiumsulphite-thioureasystem[J].MineralsEngineering,2001,14(2):263-268.
[62]DENGTL,LIAOMX.Goldrecoveryenhancementfromarefractoryflotationconcentratebysequentialbioleachingandthiourealeach[J].Hydrometallurgy,2002,63(3):249-255.
[63]龙怀中.硫脲浸金过程中亚硫酸的促进作用[J].有色金属(选矿部分),2002(5):33-36.
[64]林星,林嵩岳,田忠诚.硫脲炭浸法从低品位微细铁帽金矿提金工艺研究[J].黄金科学技术,1995，3(3):37-42.
[65]TREMBLAYL,DESCHNESG,GHALIE,etal.Goldrecoveryfromasulphidebearinggoldorebypercolationleachingwiththiourea[J].InternationalJournalofMineralProcessing,1996,48(3/4):225-244.
[66]罗仙平,邱廷省,付丽珠.磁场强化硫脲提金技术的热力学研究[J].南方冶金学院学报,1999,20(4):248-251.
[67]念保义,郑炳云.超声波强化硫脲提金的研究[J].化学工程师,2001(4):11-13.
[68]许世伟,王建英,郑升,等.泉山金矿氰化尾矿焙烧—超声波强化硫脲提金试验研究[J].黄金,2013,34(5):49-51.
[69]MURTHYDSR,KUMARV,RAOKV.ExtractionofgoldfromanIndianlow-graderefractorygoldorethroughphysicalbeneficiationandthiourealeaching[J].Hydrometallurgy,2003,68(1/2/3):125-130.
[70]CHOINC,KIMBJ,CHOK,etal.Microwavepretreatmentforthiourealeachingforgoldconcentrate[J].Metals,2017,7(10):404-412.
[71]YANGXY,MOATSMS,MILLERJD,etal.Thiourea-thiocyanateleachingsystemforgold[J].Hydrometallurgy,2010,106(1/2):58-63.
[72]杨喜云,刘政坤,郭孔彬,等.硫脲-硫氰酸钠浸出难处理金矿及浸出剂的稳定性[J].中国有色金属学报,2014,24(8):2164-2170.
[73]OLYAEIY,NOPARASTM,TONKABONISZS,etal.Responseoflow-gradegoldoretocyanidationandthiourealeaching[J].Particu-lateScienceandTechnology,2019,37(1):86-93.
[74]CHANGSH,HALIMSFA.Recoveryofpreciousmetalsfromdiscardedmobilephonesbythiourealeaching[J].MaterialsScienceForum,2019,962:112-116.
[75]RIZKIIN,TANAKAY,OKIBEN.Thioureabioleachingforgoldrecyclingfrome-waste[J].WasteManagement,2019,84:158-165.
[76]GUOXY,ZHANGL,TIANQH,etal.Stepwiseextractionofgoldandsilverfromrefractorygoldconcentratecalcinebythiourea[J].Hydrometallurgy,2020,194:105330.
[77]ADAMSCR,PORTERCP,ROBSHAWTJ,etal.Analternativetocyanideleachingofwasteactivatedcarbonashforgoldandsilverrecoveryviasynergisticdual-lixivianttreatment[J].JournalofIndustrialandEngineeringChemistry,2020,92:120-130.
[78]AHMEDMR,MOHAMMEDHS,ELFEKYMG,etal.Goldleach-ingusingthioureafromuraniumtailingmaterial,GabalElMissikat,CentralEasternDesert,Egypt[J].JournalofSustainableMetallurgy,2020,6(4):599-611.
[79]LIQ,SHENH,XUR,etal.EffectofAcidithiobacillusferrooxidansandLeptospirillumferrooxidansonpreg-robbingofgoldbygraphitefromthiourealeachingsolution[J].JournalofCleanerProduction,2020,261(7):121122.
[80]马尚文,王金中,周克泉,等.难浸金矿石的预处理Ⅰ.焙烧—硫代硫酸盐法浸取金的研究[J].黄金,1993,14(6):39-40,38.
[81]杨中民,杨春芬,王光灿.含砷难浸金矿的硫代硫酸盐法浸金[J].云南大学学报(自然科学版),1997，19(5):508-514.
[82]郑若锋,刘川,商容生,等.覆膜—铜氨硫代硫酸盐滴淋堆浸提金工艺研究[J].黄金,2005,26(11):37-40.
[83]李汝雄,邝生鲁.用金的阳极溶解方法研究氯化钠在硫代硫酸盐浸金过程中的作用[J].北京石油化工学院学报，1999，7（2）：22-25.
[84]CHANDRAI,JEFFREYMI.Afundamentalstudyofferricoxalatefordissolvinggoldinthiosulfatesolutions[J].Hydrometallurgy,2005,77(3/4):191-201.
[85]FICERIOVJ,BALP,VILLACHICACL.Thiosulfateleachingofsilver,goldandbismuthfromacomplexsulfideconcentrates[J].Hydrometallurgy,2005,77(1/2):35-39.
[86]童雄,张艮林,普传杰.氨性硫代硫酸盐浸金体系中硫代硫酸盐的消耗[J].有色金属,2005(2):69-72,77.
[87]王丹.基于控制硫代硫酸盐消耗的强化浸金研究[D].长沙:中南大学,2013.
[88]FENGD,VANDEVENTERJSJ.Thiosulphateleachingofgoldinthepresenceofethylenediaminetetraaceticacid(EDTA)[J].MineralsEngineering,2009,23(2):143-150.
[89]AAZAMIM,LAPIDUSGT,AZADEHA.TheeffectofsolutionparametersonthethiosulfateleachingofZarshouranrefractorygoldore[J].InternationalJournalofMineralProcessing,2014,131:43-50.
[90]迟衡.黄铜矿在硫代硫酸盐浸金体系中共溶及其对浸金过程的影响[D].昆明:昆明理工大学,2016.
[91]XUB,LIK,ZHONGQ,etal.Studyontheoxygenpressurealkalineleachingofgoldwithgeneratedthiosulfatefromsulfuroxidation[J].Hydrometallurgy,2018,177:178-186.
[92]WANGQ,HUXZ,ZIFT,etal.Environmentallyfriendlyextractionofgoldfromrefractoryconcentrateusingacopper-ethylenedia-mine-thiosulfatesolution[J].JournalofCleanerProduction,2019,214:860-872.
[93]XUB,LIK,LIQ,etal.Kineticstudiesofgoldleachingfromagoldconcentratecalcinebythiosulfatewithcobalt-ammoniacatalysisandgoldrecoverybyresinadsorptionfromitspregnantsolution[J].SeparationandPurificationTechnology,2019,213:368-377.
[94]XUB,LIK,DONGZL,etal.Eco-friendlyandeconomicalgoldextractionbynickelcatalyzedammoniacalthiosulfateleaching-resinadsorptionrecovery[J].JournalofCleanerProduction,2019,233:1475-1485.
[95]SITANDOO,DAIX,SENANAYAKEG,etal.Afundamentalstudyofgoldleachinginathiosulfate-oxygen-coppersysteminthepresenceofactivatedcarbon[J].Hydrometallurgy,2020,192:105232.
[96]WANGJ,WANGW,BAIYL,etal.Studyonpre-oxidationofahigh-arsenicandhigh-sulfurrefractorygoldconcentratewithpotassiumpermanganateandhydrogenperoxide[J].TransactionsoftheIndianInstituteofMetals,2020,73:577-586.
[97]ZHAOHF,YANGHY,CHENX,etal.Effectoftriethanolamineasanewandefficientadditiveonthiosulfate-copper-ammoniasystemleachingofgold[J].JOM,2020,72:946-952.
[98]HEY,HUXZ,ZIFT,etal.Solidificationofsulfurandarsenicingoldconcentrateandleachingofthegoldbythiosulfate[J].Asia-PacificJournalofChemicalEngineering,2020,15(1):2396-2410.
[99]GUIQH,KHANMI,WANGSX,etal.Theultrasoundleachingkineticsofgoldinthethiosulfateleachingprocesscatalysedbycobaltammonia[J].Hydrometallurgy,2020,196:105426.
[100]BAEM,KIMS,SOHNJ,etal.Leachingbehaviorofgoldandsilverfromconcentratedsulfideoreusingammoniumthiosulfate[J].Metals,2020,10(8):1029-1038.
[101]肖力,王永良,钱鹏,等.非氰提金技术研究进展[J].黄金科学技术,2019,27(2):292-301.
[102]鲁顺利.非氰化法提金工艺研究现状[J].云南冶金,2011,40(3):32-36,41.
[103]石嵩高.载氯体氯化法浸提金和银:CN1047346[P].1990-11-28.
[104]夏木西卡玛尔,阿不里米提,王菊芳,等.催化氯化法浸金研究[J].黄金,1997,18(9):37-39.
[105]刘春奇.水氯化法处理废载金碳[J].有色矿冶,2005(2):21-23.
[106]金创石,张廷安,曾勇,等.液氯化法从难处理金精矿加压氧化渣中浸金的研究[J].稀有金属材料与工程,2012,41(增刊2):569-572.
[107]LAMPINENM,SEISKOS,FORSSTRMO,etal.Mechanismandkineticsofgoldleachingbycupricchloride[J].Hydrometallurgy,2017,169:103-111.
[108]AHTIAINENR,LUNDSTRMJ,LIIPOK.Preg-robbingverificationandpreventioningoldchloride-bromideleaching[J].MineralsEngineering,2018,128:153-159.
[109]ALTINKAYAP,MKINENJ,KINNUNENP,etal.Effectofbiologicalpretreatmentonmetalextractionfromflotationtailingsforchlorideleaching[J].MineralsEngineering,2018,129:47-53.
[110]WANGQ,HUXZ,ZIFT,etal.Extractionofgoldfromrefractorygoldoreusingbromateandferricchloridesolution[J].MineralsEngineering,2019,136:89-98.
[111]ELOMAAH,RINTALAL,AROMAAJ,etal.Processsimulationbasedlifecycleassessmentofcyanide-freerefractorygoldconcentrateprocessing-Casestudy:Cupricchlorideleaching[J].MineralsEngineering,2020,157:106559.
[112]张文岐,熊亚东.氯化法浸金工艺研究与实践[J].中国有色冶金,2020,49(1):85-89.
[113]LIHY,YINSH,LISW,etal.Investigationontherecoveryofgoldfrompretreatedcyanidetailingsusingchlorinationleachingprocess[J].SeparationScienceandTechnology,2021,56(1):45-53.
[114]杨天足,陈希鸿,宾万达,等.多硫化钠浸金研究[J].中南矿冶学院学报,1992,23(6):687-692.
[115]龙炳清,陈希鸿,宾万达,等.多硫化物浸金研究[J].黄金,1987,8(3):33-37.
[116]白成庆.非氰浸金试剂的应用现状及发展[J].矿业快报,2008(12):12-17.
[117]朱国才,方兆珩,陈家镛.多硫化物浸取含金硫化矿的研究[J].贵金属,1994,15(2):26-31.
[118]杨天足,宾万达,陈希鸿,等.难处理金矿石加石灰焙烧焙砂的多硫化物浸出[J].黄金,1995,16(10):29-32.
[119]李洪枚,柯家骏,兰新哲.多硫化物浸金溶液中总多硫根离子浓度的测定[J].黄金,1998,19(9):3-5.
[120]郁能文,张箭.用石硫合剂法从高铅金精矿浸出金[J].贵金属,1994,15(1):10-14.
[121]陈江安,周源.某金矿石石硫合剂法浸金工艺研究[J].有色金属(选矿部分),2004(5):16-18.
[122]陈江安,周源.石硫合剂浸金体系的探讨[J].现代矿业,2009,25(1):41-42,52.
[123]刘有才,彭彬江,林清泉,等.某氰化渣的改性石硫合剂法浸金研究[J].贵金属,2016,37(1):11-14.
[124]陈怡,宋永辉.某碳质金精矿石硫合剂法浸出试验研究[J].黄金,2012,33(3):43-46.
[125]张景河.采用石硫合剂处理某难浸金矿的试验研究[J].矿业研究与开发,2020,40(4):118-121.
[126]WENQJ,WUYF,WANGX,etal.Researchesonpreparationandpropertiesofsodiumpolysulphideasgoldleachingagent[J].Hydrometallurgy,2017,171:77-85.

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湿法提金技术发展历程及应用现状

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Development history and current application status of wet gold extraction technology

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