This comprehensive review examines advances in silver analysis and determination methodologies within China from 2021 to 2024, covering perse sample types including geological samples, ores, concentrates, other sil-ver-bearing materials, water quality, and silver products/jewelry. The study highlights the application of measurement uncertainty evaluation in enhancing the accuracy and reliability of silver quantification. The study prospects the silver analysis methods from perspectives such as technological innovations, standardization initiatives, and smart analysis systems. 146 references are cited in the paper.