大兴安岭北段斑岩型钼(铜)矿床主要硫化物化学成分特征及地质意义——以770钼(铜)矿床为例
Chemical characteristics of major sulfides in porphyry-type molybdenum (copper) deposits in the Northern Greater Khingan Mountains and their geological significance — A case study of 770 Molybdenum (Copper) Deposit
-
摘要: 斑岩型钼(铜)矿床一直以来都是地质学领域的研究热点。770钼(铜)矿床是近年来在大兴安岭北段新发现的斑岩型钼(铜)矿床,目前对于该矿床的报道较少。以大兴安岭北段770钼(铜)矿床中黄铁矿和黄铜矿为研究对象,利用电子显微镜和电子探针分析技术(EPMA),深入探讨黄铁矿和黄铜矿的晶体形态和主量元素、微量元素组成,以便更全面地解析黄铁矿和黄铜矿的化学成分特征及其地质意义。770钼(铜)矿床为大型斑岩型钼(铜)矿床,矿体赋存于晚侏罗世的花岗斑岩中。从中心向外部,蚀变区域可分为钾化带和黄铁-绢英岩化带。电子探针分析结果显示,黄铁矿中w(S)普遍小于53.45 %, w(Fe)普遍小于46.55 %, w(S)/w(Fe)≥1.148,表明770钼(铜)矿床黄铁矿主要为贫铁贫硫型黄铁矿,成矿环境的硫逸度较高。黄铁矿微量元素与主量元素的正负相关性特征表明,黄铁矿中的微量元素如Zn、Mo、Ni、Co和As,通常以矿物包裹体或类质同象的形式存在于矿物中。770钼(铜)矿床中黄铁矿w(Co)/w(Ni)值(2.25~4.50)显示,其具有岩浆热液成因的性质。黄铜矿的n(Cu)+n(Fe)/n(S)值(平均值为0.91)表明,黄铜矿等金属硫化物的形成可能发生在中低温(约200 ℃)热液环境中。Abstract: Porphyry-type molybdenum (copper) deposits have long been a focus of geological studies. 770 Molybdenum (Copper) Deposit, a newly discovered porphyry-type deposit in the Northern Greater Khingan Mountains, has seen limited reporting. This study examines pyrite and chalcopyrite within 770 Molybdenum (Copper) Deposit using electron microscopy and EPMA (Electron Probe Micro-analysis) to investigate the crystal morphology and the major and trace element compositions of these sulfides, providing a comprehensive understanding of their chemical characteristics and geological significance. The 770 Molybdenum (Copper) Deposit, a large porphyry-type molybdenum (copper) deposit, has its ore bodies hosted in Late Jurassic granite porphyry. Alteration zones are divided into a central potassic zone and a peripheral pyrite-sericite zone. EPMA results show pyrite with sulfur content generally below 53.45 %, iron content below 46.55 %, and a w(S)/w(Fe) ratio ≥ 1.148, indicating that the deposit's pyrite is low-iron, low-sulfur pyrite, formed under conditions of high sulfur fugacity. The trace-to-major element correlations suggest elements like Zn, Mo, Ni, Co, and As exist in pyrite as mineral inclusions or in isomorphic forms. The w(Co)/w(Ni) ratio (2.25-4.50) in pyrite indicates a magmatic-hydrothermal origin, while the n(Cu) + n(Fe)/n(S) ratio in chalcopyrite (average 0.91) suggests formation in a mid- to low-temperature (around 200 ℃) hydrothermal environment.
下载: