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湖北省竹山县土地岭铌钽矿床矿物组成及铌钽赋存状态

Mineral composition and niobium and tantalum occurrence states in Tudiling Nb−Ta Deposit, Zhushan County, Hubei Province

  • 摘要: 土地岭铌钽矿床是湖北省近年来新发现的大型铌钽矿床,其矿物组成、铌钽矿物粒度与嵌布特征、赋存状态等基础矿物学研究较为薄弱,严重制约了该类矿床资源高效评价与合理开发利用。通过显微镜鉴定、X射线衍射分析(XRD)及工艺矿物学参数自动定量分析(MLA)等手段,系统开展了矿石工艺矿物学研究。结果表明,铌钽矿石岩性可分为粗面质(晶屑)凝灰岩和凝灰质绢云千枚岩2类,其Nb2O5平均品位分别为0.157 %和0.114 %,Ta2O5平均品位分别为0.012 %和0.006 %。二者矿物组成相似,铌钽主要赋存于铌钽铁矿和铌金红石中,其中凝灰质绢云千枚岩中可见少量贝塔石。铌钽主要以独立矿物形式存在于铌钽铁矿中,其次以类质同象形式分布于铌金红石中。铌钽矿物嵌布粒度普遍细微,且解离程度低,绝大多数颗粒的解离度不足25 %,主要与钠长石、白云母呈两相或多相连生,选矿分离难度较大。研究成果为后续资源开发利用与选矿工艺优化提供了关键科学依据。

     

    Abstract: The Tudiling Nb−Ta Deposit is a large-scale Nb−Ta deposit newly discovered in Hubei Province in recent years. However, its fundamental mineralogical studies, including mineral composition, grain size and embedding characteristics of Nb−Ta minerals, and their occurrence states, remain relatively weak, which severely constrains the efficient resource evaluation and rational development and utilization of this deposit type. The study systematically investigated its process mineralogy by using microscopy, X-ray diffraction (XRD), and mineral liberation analysis (MLA). The results show that the Nb−Ta ore can be classified into two lithologies: trachytic (crystal fragment) tuff and tuffaceous sericite phyllite, with average Nb2O5 grades of 0.157 % and 0.114 % and average Ta2O5 grades of 0.012 % and 0.006 %, respectively. The two rock types share similar mineral compositions, with niobium and tantalum mainly occurring in columbite-tantalite and niobian rutile, and minor betafite observed in the tuffaceous sericite phyllite. Niobium and tantalum predominantly occur as independent minerals in columbite-tantalite, and secondarily in the form of isomorphism in niobian rutile. The Nb−Ta minerals generally have fine embedding particle sizes with low liberation degrees. The vast majority of grains have liberation degrees of less than 25 % and mainly exhibit two- or multi-phase intergrowths with albite and muscovite, which makes mineral processing rather difficult. The research findings provide a critical scientific basis for subsequent resource development, utilization, and optimization of mineral processing technology.

     

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