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基于磷固废胶凝材料的固化尾矿性能试验研究

Experimental study on properties of solidified tailings using phosphorous solid waste-based cementitious materials

  • 摘要: 研究以云南某磷矿尾矿为骨料,结合全磷固废胶凝材料制备固化尾矿,旨在探究浓度和配比对其抗渗等级、抗剪强度(内聚力、内摩擦角)及抗压强度性能的影响。在磷尾矿固化过程中,在配比(m(胶凝材料)︰m(磷尾矿))相同条件下,提高浓度(从72 %提升至85 %)可显著提升固化尾矿性能;在相同浓度条件下,降低配比(从1︰10降低至1︰20)则会导致固化尾矿性能显著劣化,且劣化速率随配比降低呈非线性加剧趋势。非线性回归分析进一步证实浓度与配比对抗渗等级、抗剪强度(内聚力、内摩擦角)及抗压强度的影响具有显著的非线性特征。该研究为磷尾矿资源化利用提供了重要的试验数据和理论支撑,有助于推动磷尾矿在矿山充填等领域的应用,缓解磷尾矿堆存带来的环境与安全压力。

     

    Abstract: This study employed tailings from a phosphate mine in Yunnan as aggregates, combined with a fully phosphorous solid waste-based cementitious material to produce solidified tailings. It aims to investigate the effects of concentration and mix ratio on the impermeability grade, shear strength (cohesion and internal friction angle), and compressive strength of the solidified tailings. During the solidification process, under the same mix ratio (m (cementitious material)︰m (phosphate tailings)), increasing the concentration (from 72 % to 85 %) significantly enhanced the performance of the solidified tailings. Under the same concentration conditions, reducing the mix ratio (from 1︰10 to 1︰20) led to a significant deterioration in the performance of the solidified tailings, with the deterioration rate accelerating nonlinearly as the mix ratio decreased. Nonlinear regression analysis further confirmed that the effects of concentration and mix ratio on impermeability grade, shear strength (cohesion and internal friction angle), and compressive strength exhibit significant nonlinear characteristics. This research provides important experimental data and theoretical support for the resource utilization of phosphate tailings, contributing to their application in areas such as mine backfilling and alleviating the environmental and safety pressures associated with phosphate tailings storage.

     

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