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激发药剂在矿渣基胶结材料中速凝早强机理试验研究

Experimental study on the mechanism of rapid setting and early strength development of activating agents in ore residue-based cementitious materials

  • 摘要: 以尾砂、矿渣基胶结材料为原材料,研究水玻璃、NaOH、Na2SO4、Al2(SO4)3 4种无机盐激发药剂在不同掺量下的速凝早强效果,并解释其早强机理。研究发现:4种激发药剂在一定的添加范围内,充填体试块的抗压强度随龄期的增长而增大。掺量0.5 %的NaOH早强效果最好,掺量1.0 %的Na2SO4效果次之,掺量0.5 %的Al2(SO4)3对后期强度增长作用最明显,水玻璃效果最差。同时考虑到实用性、经济性,复合使用Na2SO4和Al2(SO4)3添加到尾砂胶结充填体试块中,综合性能较好。研究结果可有效提高充填体早期强度,为矿山进行充填体结构及强度优化设计提供科学参考依据。

     

    Abstract: This study investigates the early strength development and rapid setting effects of 4 inorganic salt activating agents,namely water glass,NaOH,Na2SO4,and Al2(SO4)3,at different dosages in tailings and ore residue-based cementitious materials,elucidating their mechanisms.Results show that within a certain range of addition,the compressive strength of the filling specimens increases with age for all 4 activating agents.NaOH at a addition of 0.5 % exhibits the best early strength development,followed by Na2SO4 at 1.0 % addition,while Al2(SO4)3 at 0.5 % addition shows the most significant effect on later strength development,with water glass performing the poorest.Considering practicality and economy,the composite use of Na2SO4 and Al2(SO4)3 added to tailings-based cementitious filling specimens demonstrates superior comprehensive performance.These findings effectively enhance the early strength of backfill body,providing scientific references for optimizing the structure and strength of backfill body in mines.

     

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