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湖北某低品位含碳质金矿碱性加压预氧化—氰化浸出试验研究

Experimental study on alkaline pressure pre-oxidation-cyanide leaching of low-grade carbonaceous gold ore in Hubei Province

  • 摘要: 湖北某尾矿金品位0.325 g/t,含碳0.49 %,属典型低品位含碳质金矿。工艺矿物学表明,矿石中主要矿物组成为石英、高岭石和伊利石,79.59 %的碳质分布于有机碳中。采用直接氰化浸出、表面钝化—氰化浸出、竞争吸附—氰化浸出、化学氧化预处理—氰化浸出等浸出工艺,金浸出率均不足20 %。劫金性能试验表明,该尾矿劫金指数为1.462 g/t,属于中劫金类金矿,使用碱性加压预氧化工艺能大大降低碳质的劫金效应,提高氰化浸出金浸出率。在磨矿细度为-0.074 mm占比80 %,氧分压为1 000 kPa,液固比2∶1,氢氧化钠用量为5 %,加压预氧化时间为6 h,搅拌速度为200 r/min的条件下进行碱性加压预氧化—氰化浸出,金浸出率达到64.15 %。

     

    Abstract: The gold grade of a tailings sample in Hubei is 0.325 g/t,with a carbon content of 0.49 %,belonging to typical low-grade carbonaceous gold ore.The mineralogy indicates that the main minerals in the ore are quartz,kaolinite,and illite,with 79.59 % of carbon distributed in organic carbon.Various leaching processes such as direct cyanide leaching,surface passivation-cyanide leaching,competitive adsorption-cyanide leaching,and chemical oxidation pre-treatment-cyanide leaching were employed,but the gold leaching rates were all less than 20 %.The preg-robbing performance test shows that the tailings have a preg-robbing index of 1.462 g/t,belonging to the medium preg-robbing category.The alkaline pressure pre-oxidation process significantly reduced the carbonaceous preg-robbing effect and increased gold leaching efficiency.Under specific conditions of grinding fineness at -0.074 mm with 80 % distribution,oxygen pressure of 1 000 kPa,liquid-solid ratio of 2∶1,sodium hydroxide dosage of 5 %,and pressure pre-oxidation time of 6 h at an agitation rate of 200 r/min,the gold leaching rate reached 64.15 % by alkaline pressure pre-oxidation-cyanide leaching.

     

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