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内蒙古敖仑花钼铜矿床成矿流体来源及成矿作用机制

Source of ore-forming fluids and metallogenic mechanism in Aolunhua Mo-Cu Deposit,Inner Mongolia

  • 摘要: 敖仑花钼铜矿床为典型的斑岩型矿床,矿体主要赋存于早白垩世二长花岗斑岩中。成矿作用可以分为4个阶段:石英+黄铁矿+辉钼矿阶段(Ⅰ)、石英+辉钼矿+黄铁矿+黄铜矿阶段(Ⅱ)、石英+黄铁矿+黄铜矿+闪锌矿阶段(Ⅲ)、石英+碳酸盐脉阶段(Ⅳ)。矿物学、流体包裹体岩相学、包裹体显微测温、稳定同位素研究表明;成矿Ⅰ、Ⅱ阶段成矿流体为高温(316 ℃~462 ℃)、高盐度(2.23 %~45.54 %)的NaCl-H2O-CO2体系热液;成矿Ⅲ阶段成矿流体为高温(300 ℃~368 ℃)、低盐度(3.37 %~9.34 %)的NaCl-H2O体系热液;成矿Ⅳ阶段为低温(130 ℃~260 ℃)、低盐度(3.53 %~11.95 %)的NaCl-H2O体系热液;总体具有成矿温度、盐度逐渐降低的特征。氢、氧同位素分析结果表明,早期成矿流体以岩浆水为主,晚期逐渐混入大气降水;δ34S值为1.9 ‰~4.9 ‰,指示硫同位素主要来源可能是岩浆。由于温度、压力降低,流体发生沸腾作用,CO2挥发,流体pH升高,导致Mo、Cu等成矿元素开始沉淀,最后富集成矿。

     

    Abstract: Aolunhua Mo-Cu Deposit is a typical porphyry deposit.The ore bodies mainly occur in the monzonitic granite porphyry in the Early Cretaceous.The hydrothermal mineralization can be divided into 4 stages:quartz+pyrite+molybdenite stage(Ⅰ),quartz+molybdenite+pyrite+chalcopyrite stage(Ⅱ),quartz+pyrite+chalcopyrite+sphalerite stage(Ⅲ),quartz+carbonate veins stage(Ⅳ).The study on mineralogy,petrography of fluid inclusions,micro-thermometry of inclusions,and stable isotope analysis shows that the primary ore-forming fluids in Stage Ⅰ and Ⅱ are high temperature(316 ℃-462 ℃),high salinity(2.23 %-45.54 %)NaCl-H2O-CO2 type solutions;the ore-forming fluids in Stage Ⅲ are high temperature(300 ℃-368 ℃),low salinity(3.37 %-9.34 %)NaCl-H2O type solutions; the ore-forming fluids in Stage Ⅳ are low temperature(130 ℃-260 ℃),low salinity(3.53 %-11.95 %)NaCl-H2O type solutions,indicating the trend of decreasing ore-forming temperature and salinity.H,O isotope analysis shows that early ore-forming fluids are mainly magmatic water,meteoric water blended in later;δ34S value is 1.9 ‰-4.9 ‰,indicating magmatic source of S isotope.Due to decreasing temperature and pressure,the fluids boil,CO2 vaporizes,fluid pH increases,so that ore-forming elements such as Mo,Cu precipitates and eventually concentrates into deposits.

     

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