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氧化型与还原型矽卡岩金矿床地质与成矿特征对比研究

Comparative study on geology and metallogenic characteristics of oxidized and reduced skarn-type gold deposits

  • 摘要: 中国矽卡岩金矿床资源丰富,累计探明金储量1 871 t,占全国金储量的11 %。根据成矿侵入岩地球化学特征,矽卡岩金矿床可分为氧化型与还原型2 类。尽管前人对全球矽卡岩金矿床开展了系统性研究,但针对氧化型、还原型矽卡岩金矿床的对比分析仍显不足,其氧化还原性差异的成因机制尚不明确。通过系统梳理前人研究成果,从成矿构造背景、侵入岩特征、蚀变矿物组合、成矿流体特征及成矿模式等方面进行对比研究,得出以下结论:①2 类矽卡岩金矿床主要形成于大洋岛弧与大陆边缘造山带环境。②氧化型矽卡岩金矿床的侵入岩以高氧逸度(fO2>(fO2(FMQ)+2))、磁铁矿发育为特征,全岩w(Fe2O3)/w(Fe2O3+Fe O)>0.4;而还原型矽卡岩金矿床的侵入岩以发育钛铁矿及磁黄铁矿为主,w(Fe2O3)/w(Fe2O3+Fe O)≪0.75。③氧化型矽卡岩金矿床矽卡岩蚀变以透辉石为主,石榴子石含量显著高于辉石,金属元素组合为Au-Cu-Mo-Pb-Zn;还原型矽卡岩金矿床矽卡岩蚀变则以钙铁辉石为主,辉石与石榴子石含量相近,金属元素组合为Au-As-Te-Bi。④2 类矽卡岩金矿床成矿流体均呈现高温高盐度向中低温低盐度演化的趋势,但还原型矽卡岩金矿床流体富含CH4。⑤矽卡岩金矿床成矿模式表现为高温富金属热液岩浆流体,通过构造驱动形成进矽卡岩蚀变(石榴子石、透辉石等);随温度降低,在矽卡岩蚀变(含水硅酸盐矿物)主导下,岩石破裂促进金银等矿化形成,最终低温阶段大气降水混入,形成石英-碳酸盐脉,标志成矿结束。不同的是,氧化型矽卡岩金矿床常伴随铜钼矿化形成,而还原型矽卡岩金矿床则常伴有钨锡矿化产出。通过进一步总结矽卡岩金矿床研究中存在的科学问题,提出未来需结合扩散年代学、矿物纳米结构分析及机器学习等前沿技术深化成矿机制研究。

     

    Abstract: China is rich in skarn-type gold deposits, with cumulative proven gold reserves of 1 871 t, accounting for 11 % of the national gold reserves. According to the geochemical characteristics of ore-forming intrusive rocks, skarn-type gold deposits can be divided into oxidized and reduced types. Although previous studies have systematically investigated global skarn-type gold deposits, comparative analysis of oxidized and reduced skarn-type gold deposits remains insufficient, and the genetic mechanism of their redox differences is still unclear. By systematically reviewing previous research results, this paper conducts a comparative study from the aspects of metallogenic tectonic setting, intrusive rock characteristics, alteration mineral assemblage, ore-forming fluid characteristics, and metallogenic model, and draws the following conclusions: ① The two types of skarn-type gold deposits are mainly formed in oceanic island arc and continental margin orogenic belt environments. ② The intrusive rocks of oxidized skarn-type gold deposits are characterized by high oxygen fugacity (fO2 > (fO2(FMQ) + 2)) and magnetite development, with whole-rock w(Fe2O3)/w(Fe2O3 + FeO) > 0.4; while the intrusive rocks of reduced skarn-type gold deposits are dominated by ilmenite and pyrrhotite, with w(Fe2O3)/w(Fe2O3 + FeO) ≪ 0.75. ③ The skarn alteration of oxidized skarn-type gold deposits is dominated by diopside, with garnet content significantly higher than pyroxene, and the metal element assemblage is Au-Cu-Mo-Pb-Zn; the skarn alteration of reduced skarn-type gold deposits is dominated by hedenbergite, with similar contents of pyroxene and garnet, and the metal element assemblage is Au-As-Te-Bi. ④ The ore-forming fluids of both types of skarn-type gold deposits show a trend of evolution from high temperature and high salinity to medium-low temperature and low salinity, but the fluids of reduced skarn-type gold deposits are rich in CH4. ⑤ The metallogenic model of skarn-type gold deposits is characterized by high-temperature metal-rich hydrothermal magmatic fluids, which form prograde skarn alteration (garnet, diopside, etc.) through tectonic driving; with decreasing temperature, under the dominance of retrograde skarn alteration (hydrous silicate minerals), rock fracturing promotes the formation of gold-silver mineralization, and finally, in the low-temperature stage, meteoric water mixes in to form quartz-carbonate veins, marking the end of mineralization. The difference is that oxidized skarn-type gold deposits are often accompanied by copper-molybdenum mineralization, while reduced skarn-type gold deposits are often accompanied by tungsten-tin mineralization. By further summarizing the scientific problems existing in the study of skarn-type gold deposits, it is proposed that future research should combine frontier technologies such as diffusion chronology, mineral nanostructure analysis, and machine learning to deepen the study of metallogenic mechanisms.

     

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